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Insight of chemical environmental risk and its management from the vinyl chloride accident

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 4, doi: 10.1007/s11783-023-1652-x

Abstract: The combustion of vinyl chloride (VC) after the train derailment accident in Ohio, USA in February, 2023

Keywords： Vinyl chloride     Combustion     Chemical safety management     Environmental risk     Emerging contaminants    

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Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 4,   Pages 514-520 doi: 10.1007/s11705-011-1114-z

Abstract: Polyvinyl chloride (PVC) has become the third most used plastic after polyethylene and polypropylenePolyvinyl chloride is produced by polymerization of the vinyl chloride monomer (VCM), which is manufacturedHowever, the industrial production of VCM utilizes a mercuric chloride catalyst to promote the reactionof acetylene and hydrogen chloride.During the hydrochlorination, the highly toxic mercuric chloride tends to sublime, resulting in the deactivation

Keywords： polyvinyl chloride     vinyl chloride monomer     acetylene hydrochlorination     non-mercury catalysts     green chemical    

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Carcinogens that induce the A:T>T:A nucleotide substitutions in the genome

Guangbiao Zhou, Xinchun Zhao

Frontiers of Medicine 2018, Volume 12, Issue 2,   Pages 236-238 doi: 10.1007/s11684-017-0611-y

Abstract: ., tobacco carcinogens 4-aminobiphenyl and 1,3-butadiene, air toxic vinyl chloride and its reactive metabolitesSince tobacco smoke is a worldwide public health threat and vinyl chloride distributes globally and is

Keywords： genomic signature     carcinogen     aristolochic acid     tobacco smoke     vinyl chloride     hepatocellular carcinoma    

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Uncovering the effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content on

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1484-1502 doi: 10.1007/s11705-023-2331-y

Abstract: Various hydrophilic poly(ethylene-co-vinyl alcohol) (EVOH) were used herein to precisely control theParticularly, to prepare pristine PSF and PSF/EVOH blends with increasing vinyl alcohol (VOH: 73%, 68%

Keywords： polysulfone     blend modification     ultrafiltration membrane     formation hydrodynamics     poly(ethylene-co-vinyl    

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Molecular diffusion in ternary poly(vinyl alcohol) solutions

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 1003-1016 doi: 10.1007/s11705-021-2121-3

Abstract: The diffusion kinetics of a molecular probe—rhodamine B—in ternary aqueous solutions containing poly(vinylFor ternary poly(vinyl alcohol) solutions containing cationic or anionic surfactant, surfactant–polymer

Keywords： fluorescence correlation spectroscopy     poly(vinyl alcohol)     anomalous diffusion     crowding effects     dynamic    

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Toughening of vinyl ester resins by two-dimensional MXene nanosheets

Frontiers of Chemical Science and Engineering   Pages 1651-1658 doi: 10.1007/s11705-022-2208-5

Abstract: Two-dimensional nanosheets are highly effective tougheners for vinyl ester resins.propytrimethoxysilane (Kh-560) was used to modify MXene nanosheets (M-MXene) for use in toughening vinylester resin and vinyl ester resin modified with MXene and M-MXene were investigated.The tensile and flexural strengths of the MXene-nanosheet-modified vinyl ester resin were 27.20% and25.32% higher, respectively, than those of the neat vinyl ester resin.

Keywords： MXene nanosheets     2D material     vinyl ester resin     modification     coupling agent    

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Evaluating effect of chloride attack and concrete cover on the probability of corrosion

Sanjeev Kumar VERMA, Sudhir Singh BHADAURIA, Saleem AKHTAR

Frontiers of Structural and Civil Engineering 2013, Volume 7, Issue 4,   Pages 379-390 doi: 10.1007/s11709-013-0223-9

Abstract: recently performed chlorination studies, and from results of a field survey evaluates the effect of chloridecontent on the probability of corrosion and the influence of concrete compressive strength on the chloridecontent and penetration, also evaluates the effect of concrete cover over the chloride content of the

Keywords： concrete     chloride     reinforcement     corrosion     deterioration     cover    

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Chloride binding and time-dependent surface chloride content models for fly ash concrete

S. MUTHULINGAM,B. N. RAO

Frontiers of Structural and Civil Engineering 2016, Volume 10, Issue 1,   Pages 112-120 doi: 10.1007/s11709-015-0322-x

Abstract: embedded rebars is a classical deterioration mechanism of reinforced concrete structures exposed to chlorideChloride ingress into concrete, essential for inducing rebar corrosion, is a complex interaction betweenchloride content under tidal exposure condition; and 2) chloride binding.First, inconsistencies in surface chloride content and chloride binding models reported in literatureSecondly, to avoid such inconsistencies, surface chloride content and chloride binding models for fly

Keywords： binding isotherms     chloride ingress     concrete     fly ash     surface chloride content    

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On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

Frontiers in Energy 2010, Volume 4, Issue 2,   Pages 181-184 doi: 10.1007/s11708-009-0065-2

Abstract: A calcium chloride solution with a different extender, which is made up of either pure calcium chloride, calcium chloride with expanded graphite, or calcium chloride with activated carbon, acts differentlyThe mass ratio between calcium chloride with expanded graphite or activated carbon is almost 4∶, calcium chloride with expanded graphite, and calcium chloride with activated carbon, the strongest, the weakest oxidation creation happened in the solution of calcium chloride with activated carbon,

Keywords： stainless steel     corrosion     calcium chloride     expanded graphite     activated carbon     oxidation creation     pitting    

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Green process to recover magnesium chloride from residue solution of potassium chloride production plant

WANG Lin, HE Yunliang, WANG Yanfei, BAO Ying, WANG Jingkang

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 4,   Pages 385-389 doi: 10.1007/s11705-008-0079-z

Abstract: The green process to recover magnesium chloride from the residue solution of a potassium chloride productionThe residue solution contains magnesium chloride above 25 wt-%, potassium chloride and sodium chlorideremoval operation and the two-stage evaporation-cooling crystallization procedure to produce magnesium chlorideThe crystallized impurity carnallite obtained from the first step is recycled to the potassium chlorideThe produced magnesium chloride is up to industrial criteria.

Keywords： industrial production     chemical industrial     produced magnesium     chloride production     impurity carnallite    

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Metal cation removal by P(VC-r-AA) copolymer ultrafiltration membranes

Nachuan Wang, Jun Wang, Peng Zhang, Wenbin Wang, Chuangchao Sun, Ling Xiao, Chen Chen, Bin Zhao, Qingran Kong, Baoku Zhu

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 2,   Pages 262-272 doi: 10.1007/s11705-017-1682-7

Abstract: A series of amphiphilic copolymers containing poly(vinyl chloride-r-acrylic acid) (P(VC-r-AA) ) was synthesized

Keywords： poly(vinyl chloride-r-acrylic acid)     negatively charged PVC membrane     anti-fouling     heavy metal adsorption    

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Coupled diffusion of chloride and other ions in saturated concrete

Nattapong DAMRONGWIRIYANUPAP, Linyuan LI, Yunping XI

Frontiers of Structural and Civil Engineering 2011, Volume 5, Issue 3,   Pages 267-277 doi: 10.1007/s11709-011-0112-z

Abstract: Corrosion of reinforcing steel due to chloride ions is one of the severe deterioration problems in long-termThe diffusion of chloride ions is associated and strongly affected by other ions in the pore solutionIn this paper, chloride penetration into concrete structures was mathematically characterized by theNernst-Planck equation which considered not only diffusion mechanism of the chloride ions but also ionicThe material models of chloride binding capacity and chloride diffusion coefficient were incorporated

Keywords： diffusion     chloride     concrete     Nernst-Planck equation     durability    

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Long-term durability of onshore coated concrete —chloride ion and carbonation effects

Seyedhamed SADATI,Mehdi K. MORADLLO,Mohammad SHEKARCHI

Frontiers of Structural and Civil Engineering 2016, Volume 10, Issue 2,   Pages 150-161 doi: 10.1007/s11709-016-0341-2

Abstract: Surface chloride ion build-up and variation in chloride ion diffusion were monitored with respect to

Keywords： carbonation     chloride ion     corrosion     service life     surface coating    

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Impacts of climate change on optimal mixture design of blended concrete considering carbonation and chloride

Xiao-Yong WANG

Frontiers of Structural and Civil Engineering 2020, Volume 14, Issue 2,   Pages 473-486 doi: 10.1007/s11709-020-0608-5

Abstract: Second, strength, slump, carbonation, and chloride ingress models are used to evaluate concrete propertiesThe effect of different climate change scenarios on carbonation and chloride ingress is considered.

Keywords： ternary blended concrete     climate change     optimal mixture design     carbonation     chloride ingress    

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Decomposition of perfluorooctanoic acid by microwave-activated persulfate: Effects of temperature, pH, and chloride

Yuchi LEE, Shanglien LO, Jeff KUO, Chinghong HSIEH

Frontiers of Environmental Science & Engineering 2012, Volume 6, Issue 1,   Pages 17-25 doi: 10.1007/s11783-011-0371-x

Abstract: The objectives of this study were to investigate the effects of pH (pH= 2.5, 6.6, 8.8, and 10.5), chlorideBoth high pH and chloride concentrations would result in more scavenging of sulfate free radicals andWhen chloride concentrations were less than 0.04 mol·L at 90°C and 0.06 mol·L at 60°C, presence ofchloride ions had insignificant impacts on PFOA degradation.beyond these concentration levels, PFOA degradation rates reduced significantly with an increase in chloride

Keywords： microwave     perfluorooctanoic acid     pH     persulfate     chloride ions     perfluorocarboxylic acids    

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Title Author Date Type Operation

Insight of chemical environmental risk and its management from the vinyl chloride accident

Journal Article

Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Journal Article

Carcinogens that induce the A:T>T:A nucleotide substitutions in the genome

Guangbiao Zhou, Xinchun Zhao

Journal Article

Uncovering the effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content on

Journal Article

Molecular diffusion in ternary poly(vinyl alcohol) solutions

Journal Article

Toughening of vinyl ester resins by two-dimensional MXene nanosheets

Journal Article

Evaluating effect of chloride attack and concrete cover on the probability of corrosion

Sanjeev Kumar VERMA, Sudhir Singh BHADAURIA, Saleem AKHTAR

Journal Article

Chloride binding and time-dependent surface chloride content models for fly ash concrete

S. MUTHULINGAM,B. N. RAO

Journal Article

On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

Journal Article

Green process to recover magnesium chloride from residue solution of potassium chloride production plant

WANG Lin, HE Yunliang, WANG Yanfei, BAO Ying, WANG Jingkang

Journal Article

Metal cation removal by P(VC-r-AA) copolymer ultrafiltration membranes

Nachuan Wang, Jun Wang, Peng Zhang, Wenbin Wang, Chuangchao Sun, Ling Xiao, Chen Chen, Bin Zhao, Qingran Kong, Baoku Zhu

Journal Article

Coupled diffusion of chloride and other ions in saturated concrete

Nattapong DAMRONGWIRIYANUPAP, Linyuan LI, Yunping XI

Journal Article

Long-term durability of onshore coated concrete —chloride ion and carbonation effects

Seyedhamed SADATI,Mehdi K. MORADLLO,Mohammad SHEKARCHI

Journal Article

Impacts of climate change on optimal mixture design of blended concrete considering carbonation and chloride

Xiao-Yong WANG

Journal Article

Decomposition of perfluorooctanoic acid by microwave-activated persulfate: Effects of temperature, pH, and chloride

Yuchi LEE, Shanglien LO, Jeff KUO, Chinghong HSIEH

Journal Article